I totally agree with you about tap water Lachie3112, and I too am aware that frogs can cope with some pretty crappy conditions. I also, when I kept several species of frog at the WA Museum, used tap water when giving them a clean up. However, the big sleeper is the potential to expose these animals to Chytrid fungus when using "natural" water collected away from the area in which the frog was found. There is evidence that some species of frogs are bouncing back in numbers in areas where they were almost extinct, according to my friends at Taronga, so the prospect of Chytrid-immune populations of some species is looking promising, but we should all be aware of the damage this pathogen has caused worldwide, and take steps to ensure we don't help spread it further. Better to be cautious than sorry, not that anyone spreading Chytrid would ever be aware that they were doing it.
Jamie