Hehe they originate from South America, Venezuela precisely. They were introduced to Hawaii and specimens were collected in Hawaii and introduced to Eastern Australia around 1935 to control the cane beetle. Epic fail considering cane beetles occupy the upper half of the sugar cane stems (over 1m off the ground) and cane toads are strictly surface dwelling... they aren't arboreal, do not climb to take prey.
Interestingly though, they have been introduced to many places for biological control of Cane Beetles to protect sugar cane, and in many cases they were quite successful. In terms of their intended purpose it was a pretty reasonable guess that they might have successfully dealt with the beetles, but it was always going to be an ecological disaster. That's easy to see in hindsight, but at the time there was very limited understanding (or care) of ecology.